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ID: 16912.0, MPI für biophysikalische Chemie / Spektroskopie und photochemische Kinetik (Prof. Jürgen Troe)
A simple kinetic model of preferential solvation in binary mixtures
Authors:Petrov, N. K.; Wiessner, A.; Staerk, H.
Language:English
Date of Publication (YYYY-MM-DD):2001-12-07
Title of Journal:Chemical Physics Letters
Volume:349
Issue / Number:5-6
Start Page:517
End Page:520
Review Status:Peer-review
Audience:Not Specified
Abstract / Description:Based on experimental data a kinetic model is presented that adequately describes the main features of preferential solvation of a charge-transfer dipole in binary mixtures. 8- (N,N-dimethylamino)-11H-indeno[2,1-a]pyrene is used as fluorescent probe in toluene/DMSO mixtures. The observed saturation behavior can be understood in terms of microclusters of polar molecules surrounding the solute dipolar species. In such an approach, the size of the microclusters is mainly determined by interfacial surface tension. (C) 2001 Published by Elsevier Science B.V.
Comment of the Author/Creator:Date: 2001, DEC 7
External Publication Status:published
Document Type:Article
Communicated by:N. N.
Affiliations:MPI für biophysikalische Chemie/Abt. Jürgen Troe / 010
External Affiliations:Russian Acad Sci, Photochem Ctr, Moscow 117344, Russia
Identifiers:URL:http://www.sciencedirect.com/science?_ob=MImg&_ima...
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