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ID: 299341.2, MPI für Dynamik komplexer technischer Systeme / Physical and Chemical Foundations of Process Engineering
Thermal effects in reactive liquid chromatography
Authors:Sainio, T.; Kaspereit, M.; Kienle, A.; Seidel-Morgenstern, A.
Language:English
Date of Publication (YYYY-MM-DD):2007
Title of Journal:Chemical Engineering Science
Volume:62
Issue / Number:18-20 - Special Issue : 19th International Symposium on Chemical Reaction Engineering - From Science to Innovative Engineering - ISCRE-19
Start Page:5674
End Page:5681
Review Status:Peer-review
Audience:Experts Only
Abstract / Description:Thermal effects in unsteady-state liquid phase chromatographic reactors were investigated experimentally in a thermally insulated column. In the case of an exothermic esterification reaction catalyzed by an acidic ionexchange resin, a self-amplifying positive thermal wave was found to develop in the reactor. This improved the reactor performance considerably when compared to isothermal conditions. The heat of reaction, enthalpy of adsorption, and heat of mixing all contribute to the thermal behavior of the reactor. The complex dynamic behavior caused by non-isothermal operation was elucidated by means of numerical simulations. The solid phase to fluid phase heat capacity ratio was found to be an important parameter because it affects the magnitude and propagation velocities of the thermal waves.

SciVerse® is a registered trademark of Elsevier Properties S.A., used under license. ScienceDirect® is a registered trademark of Elsevier B.V. [accessed February 8th 2013]
Free Keywords:chromatographic reactor; non-isothermal reactor; thermal effects; process intensification; ion-exchange resin; esterification
External Publication Status:published
Document Type:Article
Communicated by:Andreas Seidel-Morgenstern
Affiliations:MPI für Dynamik komplexer technischer Systeme/Process Synthesis and Process Dynamics
MPI für Dynamik komplexer technischer Systeme/Physical and Chemical Foundations of Process Engineering
External Affiliations:Laboratory of Industrial Chemistry, Lappeenranta University of Technology, Lappeenranta, Finland

Otto-von-Guericke-Universität Magdeburg,
Institut für Automatisierungstechnik,
Magdeburg, Germany

Otto-von-Guericke-Universität Magdeburg,
Institut für Verfahrenstechnik,
Magdeburg, Germany
Identifiers:LOCALID:15/07
URL:http://dx.doi.org/10.1016/j.ces.2007.02.033
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