Home News About Us Contact Contributors Disclaimer Privacy Policy Help FAQ

Home
Search
Quick Search
Advanced
Fulltext
Browse
Collections
Persons
My eDoc
Session History
Login
Name:
Password:
Documentation
Help
Support Wiki
Direct access to
document ID:


          Institute: Fritz-Haber-Institut     Collection: Molecular Physics     Display Documents



  history
ID: 174131.0, Fritz-Haber-Institut / Molecular Physics
Structure Determination of Isolated Metal Clusters via Far-Infrared Spectroscopy
Authors:Fielicke, André; Kirilyuk, Andrei; Ratsch, Christian; Behler, Jörg; Scheffler, Matthias; von Helden, Gert; Meijer, Gerard
Language:English
Date of Publication (YYYY-MM-DD):2004-07-07
Title of Journal:Physical Review Letters
Journal Abbrev.:Phys. Rev. Lett.
Volume:93
Issue / Number:2
Start Page:023401-1
End Page:023401-4
Copyright:2004 The American Physical Society
Review Status:Peer-review
Audience:Experts Only
Abstract / Description:We present a new method for the size selective structure determination of small isolated metal clusters in the gas phase. The technique is applied to cationic vanadium clusters containing 6 to 23 atoms, whose far infrared absorption spectra are measured in the 140–450 cm–1 spectral range. The spectra are unique for each cluster size and are true fingerprints of the cluster's structure. By comparing the experimental spectra to spectra obtained from density-functional theory, the geometric cluster structure can be identified.
External Publication Status:published
Document Type:Article
Communicated by:Gerard Meijer
Affiliations:Fritz-Haber-Institut/Molecular Physics
Fritz-Haber-Institut/Theory
External Affiliations:FOM Institute for Plasma Physics Rijnhuizen, Nieuwegein, The Netherlands; NSRIM Institute, University of Nijmegen, Nijmegen, The Netherlands; Department of Mathematics, UCLA, Los Angeles, California, USA
Identifiers:URL:http://scitation.aip.org/getabs/servlet/GetabsServ...
DOI:10.1103/PhysRevLett.93.023401
Full Text:
You have privileges to view the following file(s):
e023401.pdf  [172,00 Kb]   
 
The scope and number of records on eDoc is subject to the collection policies defined by each institute - see "info" button in the collection browse view.