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          Institute: MPI für Chemische Physik fester Stoffe     Collection: publications 2002     Display Documents



ID: 18261.0, MPI für Chemische Physik fester Stoffe / publications 2002
Cs2[PdCl4] - neue Ergebnisse zu einer "altbekannten" Verbindung
Translation of Title:Cs<sub>2</sub>[PdCl<sub>4</sub>] - New results on a "wellkown" compound
Authors:Schüpp, B.; Schröder, L.; Schulte, H.; Bähtz, C.; Mattern, N.; Keller, H. L.
Language:German
Date of Publication (YYYY-MM-DD):2002-07
Title of Journal:Zeitschrift für Anorganische und Allgemeine Chemie
Journal Abbrev.:Z. Anorg. Allg. Chem.
Volume:628
Issue / Number:7
Start Page:1708
End Page:1714
Review Status:Peer-review
Audience:Not Specified
Abstract / Description:Two modifications of Cs-2[PdCl4] have been characterized by X- ray powder and single crystal diffraction, respectively. The crystal structures are described and the group-subgroup- relations between these structures are discussed. In addition to the tetragonal (P4/mmm (No. 123), a 7.4158(8) Angstrom, c = 4.6792(6) Angstrom) and the orthorhombic (Cmcm (No. 63), a = 10.529(1) Angstrom, b = 10.310(1) Angstrom, c = 9.460(1) Angstrom) modification DSC investigations and high-temperature X-ray diffraction experiments with synchrotron radiation show the existence of another modification or of yet unknown decomposition products. The phase transformation from the orthorhombic to the tetragonal polymorph is completely finished at 100degreesC. The second effect is detected at 319degreesC.
Free Keywords:cesium; palladium; dicesiumtetrachloropalladate(II)
Comment of the Author/Creator:Date: 2002, JUL
External Publication Status:published
Document Type:Article
Communicated by:Ina Wanschura
Affiliations:MPI für chemische Physik fester Stoffe
External Affiliations:Univ Dortmund, Fachbereich Chem Anorgan Chem, D-44221 Dortmund,; Germany; Univ Dortmund, Fachbereich Chem Anorgan Chem, D-44221 Dortmund, Germany; Inst Festkoper & Werkstofforsch, Dresden, Germany; Max Planck Inst Chem Phys Stoffe, Dresden, Germany; TU Darmstadt, Fachbereich Mat & Geowissensch, Darmstadt, Germany
Identifiers:ISI:000177041600046 [ID No:1]
ISSN:0044-2313 [ID No:2]
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