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          Institute: MPI für Chemie     Collection: Publikationen MPI für Chemie     Display Documents



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ID: 18269.0, MPI für Chemie / Publikationen MPI für Chemie
Dark production: A significant source of oceanic COS
Authors:von Hobe, M.; Cutter, G. A.; Kettle, A. J.; Andreae, M. O.
Language:English
Date of Publication (YYYY-MM-DD):2001-12-15
Title of Journal:Journal of Geophysical Research
Journal Abbrev.:J. Geophys. Res.
Volume:106
Issue / Number:C12
Start Page:31217
End Page:31226
Review Status:Peer-review
Audience:Experts Only
Abstract / Description:Carbonyl sulfide (COS) in air and dissolved in seawater was determined during a cruise in August 1999 in the Sargasso Sea in the northwest Atlantic Ocean. Dissolved concentrations at the sea surface displayed only a weak diel cycle with a mean of 8.6 +/- 2.8 pmol dm(-3) owing to low abundance of photochemical precursors and high temperatures causing rapid hydrolysis. Depth profiles measured over the oceanic mixed layer revealed significant vertical gradients of COS concentration with higher values at the surface, suggesting that the rate of photochemical production at the surface exceeds the rate of vertical mixing. The mean atmospheric mixing ratio was 486 +/- 40 ppt, and calculated sea-air fluxes ranged from 0.03 to 0.8 g COS km(-2) d(-1). COS dark production, estimated from the predawn COS concentration at the surface and the hydrolysis constant, contributed significantly to the total amount of COS produced. A strong temperature dependence of the COS dark production rate q was found by comparing previously published values. The data further indicate an approximately first-order relationship between q and chromophoric dissolved organic matter (CDOM) absorbance at 350 rim, alpha(350), which is used as a proxy for the CDOM content of the water but is likely to covary with other parameters, such as biological activity, that could also affect COS dark production. Together with known functions for COS hydrolysis and solubility, the parameterization of dark production as a function of temperature and alpha(350) allows for the prediction of COS concentrations and saturation ratios as a function of physical and optical seawater properties in the absence of photoproduction. This is used to estimate a lower limit of 0.056 Tg COS yr(-1) to the annual COS flux from the ocean to the atmosphere.
Free Keywords:COS preprint
External Publication Status:published
Document Type:Article
Communicated by:N. N.
Affiliations:MPI für Chemie/Biogeochemie
External Affiliations:Forschungszentrum Julich, ICG-I, D-52425 Julich, Germany; Old Dominion Univ, Dept Ocean Earth & Atmospher Sci, Norfolk, VA 23529 USA
Identifiers:ISI:000173402400022
ISSN:0148-0227
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