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          Institute: MPI für Festkörperforschung     Collection: FKF Publikationen 2004     Display Documents



  history
ID: 192733.0, MPI für Festkörperforschung / FKF Publikationen 2004
Triapua-1κO,2κO,3κO-hexakis-μ-chloroacetato-1:2κ4O:O';2:3κ4O:O';1:3κ4O:O'-μ3-oxo-triiron(III) nitrate trihydrate
Authors:Ren, X.-M.; Okudera, H.; Kremer, R. K.
Language:English
Date of Publication (YYYY-MM-DD):2004
Title of Journal:Acta Crystallographica E
Volume:60
Start Page:M14
End Page:M16
Review Status:not specified
Audience:Not Specified
Abstract / Description:The title compound, [Fe3O(C2H2ClO2)(6)(H2O)(3)]NO3.3H(2)O, contains an
Fe-III trimeric cation in which the three Fe-III ions are at the
corners of a slightly distorted triangle with an O atom in the centre.
Two monochloroacetate ligands bridge each pair of Fe-III ions and a
water molecule coordinates each Fe-III ion at the apex, opposite to the
central O atom. Hence, the Fe-III ions are surrounded by distorted
oxygen octahedra. The distances between the Fe-III ions and the central
O atoms are considerably shorter than those between the Fe-III ions and
the other coordinated O atoms. The trimeric cations form a
three-dimensional connected network via hydrogen-bonding interactions
to extra-cluster water molecules and nitrate anions.
External Publication Status:published
Document Type:Article
Communicated by:Michaela Asen-Palmer
Affiliations:MPI für Festkörperforschung
External Affiliations:Max Planck Inst Festkorperforsch, D-70569 Stuttgart, Germany.
Identifiers:ISI:000187552200009 [ID No:1]
ISSN:1600-5368 [ID No:2]
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