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          Institute: MPI für Festkörperforschung     Collection: FKF Publikationen 2004     Display Documents



  history
ID: 192865.0, MPI für Festkörperforschung / FKF Publikationen 2004
Ti5Se4: The first step of cluster condensation with titanium selenides
Authors:He, M.; Simon, A.; Duppel, V.
Language:English
Date of Publication (YYYY-MM-DD):2004
Title of Journal:Zeitschrift für anorganische und allgemeine Chemie
Volume:630
Issue / Number:4
Start Page:535
End Page:540
Review Status:not specified
Audience:Not Specified
Abstract / Description:A new Ti5Te4-type Compound, Ti5Se4, has been identified and its
structure is refined against x-ray powder diffraction data with the
Rietveld method. It has a body-centered tetragonal unit cell with
lattice parameters a = 9.6728(1) Angstrom, c = 3.5083(1) Angstrom,
space group I4/m. This compound is the first titanium selenide which
consists of separated M5X4 (M = metal, X = metalloid) chains. The
effect of atomic radii on the formation of the Ti5Te4-type structure is
discussed.
Free Keywords:titanium; selenium; Ti5Se4; Ti5Te4-type structure; metal-metal
interactions; cluster compounds
External Publication Status:published
Document Type:Article
Communicated by:Michaela Asen-Palmer
Affiliations:MPI für Festkörperforschung
External Affiliations:Max Planck Inst Festkorperforsch, D-70569 Stuttgart, Germany.
Identifiers:ISI:000220787700008 [ID No:1]
ISSN:0044-2313 [ID No:2]
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