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          Institute: MPI für Festkörperforschung     Collection: FKF Publikationen 2004     Display Documents



  history
ID: 192940.0, MPI für Festkörperforschung / FKF Publikationen 2004
Synthesis and structure of sodium tetraoxo nitrido molybdate, Na5MoO4N
Authors:Arumugam, N.; Peters, E.-M.; Jansen, M.
Language:English
Date of Publication (YYYY-MM-DD):2004
Title of Journal:Zeitschrift für Naturforschung B
Volume:59
Issue / Number:3
Start Page:274
End Page:276
Review Status:not specified
Audience:Not Specified
Abstract / Description:The new oxynitride of molybdenum, Na5MoO4N was prepared from
stoichiometric mixtures of the starting materials MoO2, Na2O2 and NaN3
which were heated in a special regime up to 500 degreesC, and cooled
down slowly. Its crystal structure was solved and refined from single
crystal data (orthorhombic, Cmcm, a = 991.1(2), b = 574.3(1), c =
1067.7(2) pm, R-1 = 0.0153, wR(2) = 0.0427). The structure consists of
isolated [MoO4N](5-) rectangular pyramids which are separated by Na+
cations. This compound is structurally related to Na5WO4N which
crystallizes in space group Cmc2(1).
Free Keywords:sodium; molybdenum; oxynitrides; structure determination
External Publication Status:published
Document Type:Article
Communicated by:Michaela Asen-Palmer
Affiliations:MPI für Festkörperforschung
External Affiliations:Max Planck Inst Festkorperforsch, D-70569 Stuttgart, Germany.
Identifiers:ISI:000221567400006 [ID No:1]
ISSN:0932-0776 [ID No:2]
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