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          Institute: MPI für bioanorganische Chemie     Collection: MPI für bioanorganische Chemie     Display Documents



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ID: 20601.0, MPI für bioanorganische Chemie / MPI für bioanorganische Chemie
Preparation and photophysical studies of a fluorous phase- soluble fullerene derivative
Authors:Wilson, Stephen R.; Yurchenko, Micheal E.; Schuster, David I.; Yurchenko, Eduard N.; Sokolova, Olga; Braslavsky, Silvia E.; Klihm, Gudrun
Language:English
Date of Publication (YYYY-MM-DD):2002
Title of Journal:Journal of the American Chemical Society
Journal Abbrev.:J. Am. Chem. Soc.
Volume:124
Issue / Number:9
Start Page:1977
End Page:1981
Review Status:Peer-review
Audience:Experts Only
Abstract / Description:We report the first synthesis of a well-characterized "Teflon ponytail" fullerene adduct (3) via the Hirsch-Bingel reaction with a malonate bearing two pefluorinated alkyl chains, This C tris-adduct shows excellent solubility in perfluorinated solvents, such as FC-72 and FC-75. Compound 3 was found to be an efficient sensitizer for singlet oxygen formation in fluorous media, which has potential in biphasic systems and in photobiology.
Comment of the Author/Creator:Date: 2002, MAR 6
External Publication Status:published
Document Type:Article
Communicated by:N. N.
Affiliations:MPI für bioanorganische Chemie
External Affiliations:NYU, Dept Chem, New York, NY 10003 USA; Perlucid Corp, Nesconset, NY 11767 USA;
Identifiers:ISI:000174191400034 [ID No:1]
ISSN:0002-7863 [ID No:2]
DOI:10.1021/ja0119200 [ID No:3]
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