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          Institute: MPI für Plasmaphysik     Collection: Articles, Books, Inbooks     Display Documents



ID: 21154.0, MPI für Plasmaphysik / Articles, Books, Inbooks
Valence and C 1s core level photoelectron spectra of camphor
Authors:Rennie, E. E.; Powis, I.; Hergenhahn, U.; Kugeler, O.; Garcia, G.; Lischke, T.; Marburger, S.
Language:English
Date of Publication (YYYY-MM-DD):2002-09
Title of Journal:Journal of Electron Spectroscopy and Related Phenomena
Journal Abbrev.:J. Electron Spectrosc. Relat. Phenom.
Volume:125
Issue / Number:3
Start Page:197
End Page:203
Review Status:Peer-review
Audience:Experts Only
Abstract / Description:The valence photoelectron spectrum of camphor has been recorded with 95 eV synchrotron radiation, with better definition than previous He I spectra. The spectrum is interpreted by comparison with these He I results and with the aid of an outer-valence Green's Function calculation of the orbital ionization energies. These calculations closely reproduce the observed vertical ionization energies in the outer valence region. A core level spectrum of the C Is region (hv=357.9 eV) is also presented and reveals a marked shift of the carbonyl carbon relative to all others in the molecule. (C) 2002 Elsevier Science B.V. All rights reserved.
Free Keywords:UV photoelectron spectrum; core level photoemission; Green's function ionization energies; camphor
External Publication Status:published
Document Type:Article
Communicated by:N. N.
Affiliations:MPI für Plasmaphysik/Direktorium
External Affiliations:Univ Nottingham, Sch Chem, Nottingham NG7 2RD, England; Max Planck Gesell, Fritz Haber Inst, D-14195 Berlin, Germany
Identifiers:ISI:000178849500005
ISSN:0368-2048
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