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          Institute: MPI für medizinische Forschung     Collection: Forschungsgruppe Prof. Dr. Haeberlen     Display Documents



ID: 226419.0, MPI für medizinische Forschung / Forschungsgruppe Prof. Dr. Haeberlen
The low−temperature 13C and 2H spectra and relaxation rates of methyl groups depend on the azimutz of B0 in the molecular frame. Those of 1H do not. Why?
Translation of Title:The low−temperature 13C and 2H spectra and relaxation rates of methyl groups depend on the azimutz of B0 in the molecular frame. Those of 1H do not. Why?
Authors:Gutsche, Peter; Haeberlen, Ulrich
Language:English
Date of Publication (YYYY-MM-DD):2004-08-01
Title of Journal:Solid State Nuclear Magnetic Resonance
Journal Abbrev.:Solid State Nucl. Magn. Reson.
Volume:25
Issue / Number:4
Start Page:46
End Page:50
Review Status:Peer-review
Audience:Experts Only
Intended Educational Use:No
Abstract / Description:It is shown that the answer to the question asked in the title is: Because the axial symmetry axes of the H−H dipolar coupling tensors in a−CH3 group are perpendicular to the (assumed) threefold axis of the group. By contrast, those of the 13C−H dipolar and 2H quadrupolar coupling tensors are not. The use of
Free Keywords:Relaxation; Spectra; Symmetry; Permutation
Last Change of the Resource (YYYY-MM-DD):--
External Publication Status:published
Document Type:Article
Communicated by:Wulf Kaiser
Affiliations:MPI für medizinische Forschung/Forschungsgruppe Molekülkristalle
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DOI:10.1016%2Fj.ssnmr.2003.11.002
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