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| ID:
241167.1,
Fritz-Haber-Institut / Inorganic Chemistry |
| Engineered Complex Emulsion System: Toward Modulating the Pore Length and Morphological Architecture of Mesoporous Silicas |
| Authors: | Zhang, He; Sun, Junming; Ma, Ding; Weinberg, Gisela; Su, Dang Sheng; Bao, Xinhe | | Language: | English | | Research Context: | Electron microscopic investigations on the important catalytic systems | | Date of Publication (YYYY-MM-DD): | 2006 | | Title of Journal: | Journal of Physical Chemistry B | | Volume: | 110 | | Issue / Number: | 51 | | Start Page: | 25908 | | End Page: | 25915 | | Review Status: | Peer-review | | Audience: | Experts Only | | Abstract / Description: | In the complex alkane/P123/TEOS/H2O emulsion system, an emulsion engineering method to modulate pore length and morphological architecture of mesoporous materials has been built. With fine tuning of the synthetic parameters (e.g., the composition of the synthetic mixtures, temperature, stirring, etc.), a series of chemically significant mesostructures (i.e., short-pore SBA-15 materials) with tunable pore length and morphological architecture have been successfully constructed. The effects of alkane solubilizates on pore length and particle morphology are discussed. The resulting short-pore materials would have potential applications in the fields of adsorption/separation of biomolecules and inclusion chemistry of guest species, etc. | | External Publication Status: | published | | Document Type: | Article |
| Communicated by: | Robert Schlögl | | Affiliations: | Fritz-Haber-Institut/Inorganic Chemistry/Microstructure
| | External Affiliations: | State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, China
| | Identifiers: | URL:http://dx.doi.org/10.1021/jp065760w [only subscribers] | |
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