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ID:
28500.0,
MPI für Polymerforschung / MPI Polymerforschung |
Dipolar recoupling in NOESY-Type H-1-H-1 NMR experiments under HRMAS conditions |
Authors: | Thieme, K.; Zech, G.; Kunz, H.; Spiess, Hans Wolfgang; Schnell, Ingo | Language: | English | Date of Publication (YYYY-MM-DD): | 2002-05-02 | Title of Journal: | Organic Letters | Journal Abbrev.: | Org. Lett. | Volume: | 4 | Issue / Number: | 9 | Start Page: | 1559 | End Page: | 1562 | Review Status: | No review | Audience: | Not Specified | Abstract / Description: | The concept of dipolar recoupling is introduced to H-1-H-1 NOESY experiments performed under HRMAS conditions. Dipole- dipole couplings are selectively recoupled during the mixing period, while MAS ensures high resolution in the spectral dimensions. Incoherent dipolar exchange is replaced by amplified coherent processes, such that time scales for polarization transfer are shortened, and dipolar double-quantum techniques become applicable. In this way, dipole-dipole couplings, as well as J-couplings, can be individually measured. | Comment of the Author/Creator: | Date: 2002, MAY 2 | External Publication Status: | published | Document Type: | Article |
Affiliations: | MPI für Polymerforschung
| External Affiliations: | Univ Mainz, Inst Organ Chem, D-55099 Mainz, Germany
| Identifiers: | ISI:000175243900038 [ID No:1] ISSN:1523-7060 [ID No:2] LOCALID:P-02-25 | |
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