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          Institute: MPI für Festkörperforschung     Collection: FKF Publikationen 2006     Display Documents



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ID: 305981.0, MPI für Festkörperforschung / FKF Publikationen 2006
Surface-template assembly of two-dimensional metal-organic coordination networks
Authors:Stepanow, S.; Lin, N.; Barth, J. V.; Kern, K.
Language:English
Date of Publication (YYYY-MM-DD):2006
Title of Journal:Journal of Physical Chemistry B
Volume:110
Issue / Number:46
Start Page:23472
End Page:23477
Review Status:Peer-review
Audience:Not Specified
Abstract / Description:The self-assembly of iron-coordinated two-dimensional metal-organic
networks on a Cu(100) surface has been investigated by scanning
tunneling microscopy under ultra-high-vacuum conditions. We applied
three rodlike polybenzene dicarboxylic acid molecules with different
backbone lengths as organic linkers. The three linker molecules form
topologically identical rectangular networks with Fe, all comprising
iron pairs as the network nodes. Whereas the length of the linker
molecules defines the dimension of the networks, the substrate also
significantly influences the structural details, e. g., network
orientation with respect to the substrate, geometric shape of the
network cavities, Fe-carboxylate coordination configuration, and
iron-iron distance.
External Publication Status:published
Document Type:Article
Communicated by:N. N.
Affiliations:MPI für Festkörperforschung
External Affiliations:Max Planck Inst Festkorperforsch, D-70569 Stuttgart, Germany.
; Ecole Polytech Fed Lausanne, Inst Phys Nanostruct, CH-1015 Lausanne, Switzerland.
; Univ British Columbia, Adv Mat & Proc Engn Lab, Dept Chem, Vancouver, BC V6T 1Z4, Canada.
; Univ British Columbia, Adv Mat & Proc Engn Lab, Dept Phys & Astron, Vancouver, BC V6T 1Z4, Canada.
Identifiers:ISI:000242045900077 [ID No:1]
ISSN:1520-6106 [ID No:2]
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