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          Institute: MPI für biologische Kybernetik     Collection: Biologische Kybernetik     Display Documents



ID: 350422.0, MPI für biologische Kybernetik / Biologische Kybernetik
(S)-(–)-2,2‘-Bis(2-methyl­allyl­oxy)-1,1‘-binaphth­yl
Authors:Ricken, S.; Angelovski, G.; Schürmann, M.; Preut, H.; Eilbracht, P.
Date of Publication (YYYY-MM-DD):2007-02
Title of Journal:Acta Crystallographica Section E
Volume:63
Issue / Number:2
Start Page:o551
End Page:o552
Audience:Not Specified
Intended Educational Use:No
Abstract / Description:The chiral title compound, C28H26O2, with potential uses in the synthesis of aza­macroheterocycles, shows a locked S-configuration for the binaphthyl unit. The diolefinic building blocks were prepared as diallylic ethers of (S)-1,1‘-binaphthol. The dihedral angle between the least-squares planes of the bicyclic ring systems is 68.53 (3)°. The mol­ecule resides on a twofold axis.
External Publication Status:published
Document Type:Article
Communicated by:Holger Fischer
Affiliations:MPI für biologische Kybernetik/Neurophysiology (Dept. Logothetis)
Identifiers:LOCALID:4285
URL:http://www.blackwell-synergy.com/action/showPdf?su...
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