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          Institute: MPI für Chemische Physik fester Stoffe     Collection: publications 2013     Display Documents



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ID: 667526.0, MPI für Chemische Physik fester Stoffe / publications 2013
Synthesis, characterization, and thermal behavior of Cu(II) and Zn(II) complexes with (E)-2-[N'-(1-pyridin-2-yl-ethylidene)hydrazino]acetic acid (aphaOH). Crystal structure of [Zn2(aphaO)2Cl2]
Authors:Filipovic, N.; Borna, M.; Klisuric, O.; Pregelj, M.; Jagodic, M.; Andelkovic, K.; Todorovic, T.
Language:English
Date of Publication (YYYY-MM-DD):2013-01-10
Title of Journal:Journal of Coordination Chemistry
Volume:66
Issue / Number:9
Start Page:1549
End Page:1560
Review Status:not specified
Audience:Not Specified
Abstract / Description:Copper(II) and zinc(II) complexes with the condensation derivative of 2-acetylpyridine and hydrolyzed ethyl hydrazinoacetate were synthesized in a one pot reaction. Crystal structure of the zinc(II) complex was determined by single-crystal X-ray diffraction. In this binuclear complex, the ligand is coordinated via pyridine and imine nitrogen, while carboxylate oxygen is a bridge between metal centers. The fifth coordination site is occupied by a chloride, giving a distorted square pyramidal geometry around each zinc(II). The molecular structure of the copper(II) complex was determined from elemental analysis, infrared and electron paramagnetic resonance spectroscopy, molar conductivity, mass spectrometry, and measurements of the magnetic moment. Thermal behavior of both complexes was studied by thermogravimetric analysis coupled with mass spectrometer.
External Publication Status:published
Document Type:Article
Communicated by:Ina Werner
Affiliations:MPI für chemische Physik fester Stoffe
Identifiers:ISI:000318280000008 [ID No:1]
ISSN:0095-8972 [ID No:2]
DOI:10.1080/00958972.2013.786052
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