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          Institute: MPI für bioanorganische Chemie     Collection: MPI für bioanorganische Chemie     Display Documents



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ID: 712920.0, MPI für bioanorganische Chemie / MPI für bioanorganische Chemie
Molecular Structure of 1,2-Bis(trifluoromethyl)-1,1,2,2-tetramethyldisilane in the Gas, Liquid, and Solid Phases: Unusual Conformational Changes between Phases
Authors:Masters, Sarah L.; Robertson, Heather E; Wann, Derek A.; Hölbling, Margit; Hassler, Karl; Bjornsson, Ragnar; Wallevik, Sunna O; Arnason, Ingvar
Language:English
Date of Publication (YYYY-MM-DD):2015
Title of Journal:Journal of Physical Chemistry A
Journal Abbrev.:J. Phys. Chem. A
Volume:119
Issue / Number:9
Start Page:1600
End Page:1608
Review Status:Internal review
Audience:Experts Only
Abstract / Description:The molecular structure of 1,2-bis(trifluoromethyl)-1,1,2,2-tetramethyldisilane has been determined in three different phases (solid, liquid, and gas) using various spectroscopic and diffraction techniques. Both the solid-state and gas-phase investigations revealed only one conformer to be present in the sample analyzed, whereas the liquid phase revealed the presence of three conformers. The data have been reproduced using computational methods and a rationale is presented for the observation of three conformers in the liquid state.
Comment of the Author/Creator:Date: 2015, MAR 5 2015
External Publication Status:published
Document Type:Article
Version Comment:Automatic journal name synchronization
Communicated by:N. N.
Affiliations:MPI für bioanorganische Chemie
External Affiliations:[Masters,S.L.;] Univ.Canterbury, Dept.Chem., Christchurch 8104, New Zealand.
[Robertson,H.E.;] Univ.Edinburgh, Sch.Chem., Edinburgh EH9 3JJ, Midlothian, Scotland.
[Wann,D.A.;] Univ.York, Dept.Chem., York YO10 5DD, N Yorkshire, England.
[Hölbling,M.; Hassler,K.] Graz Univ.Technol., A-8010 Graz, Austria.
[Wallevik,S.O.; Arnason,I.] Univ.Iceland, Inst.Sci., IS-107 Reykjavik, Iceland.
Identifiers:ISI:000350840800020 [ID No:1]
ISSN:1089-5639 [ID No:2]
DOI:10.1021/jp507744u [ID No:3]
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