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          Institute: MPI für bioanorganische Chemie     Collection: MPI für bioanorganische Chemie     Display Documents



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ID: 712921.0, MPI für bioanorganische Chemie / MPI für bioanorganische Chemie
A trinuclear Cu-II complex with functionalized s-heptazine N-ligands: molecular chemistry from a g-C3N4 fragment
Authors:Maxwell, Lindley; Gomez-Coca, Silvia; Weyhermüller, Thomas; Panyella, David; Ruiz, Eliseo
Language:English
Date of Publication (YYYY-MM-DD):2015
Title of Journal:Dalton Transactions
Journal Abbrev.:Dalton Trans.
Volume:44
Issue / Number:36
Start Page:15761
End Page:15763
Review Status:Internal review
Audience:Experts Only
Abstract / Description:A new kind of N-ligand based on heptazine derivatives is presented. A trinuclear Cu-II complex, [(L)(2)(Cu3Cl3)-Cl-II](ClO4)(3)center dot 3CH(2)Cl(2) (L = 2,4,6-tris(di-2-pyridylamino)heptazine), utilizing a pyridine derivative of heptazine has been synthesized and characterized avoiding the inherent solubility problems of heptazine compounds. Thus, this work opens the application of such ligands either in supramolecular chemistry as a larger ligand of the widely used s-triazine derivatives or to provide molecular systems for photocatalysis as heptazine is the fundamental unit of the very promising g-C3N4 2D compound.
Comment of the Author/Creator:Date: 2015, 2015
External Publication Status:published
Document Type:Article
Version Comment:Automatic journal name synchronization
Communicated by:N. N.
Affiliations:MPI für bioanorganische Chemie
External Affiliations:[Maxwell,L.; Gomez-Coca;S.; Panyella,D. ] Univ Barcelona, Inst Recerca Quim Teor & Computac, E-08028 Barcelona, Spain.
[Ruiz,E.] Antonio Puig SA, Barcelona 08030, Spain.
Identifiers:ISI:000360471000003 [ID No:1]
ISSN:1477-9226 [ID No:2]
DOI:10.1039/c5dt02485d [ID No:3]
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