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          Institute: MPI für bioanorganische Chemie     Collection: MPI für bioanorganische Chemie     Display Documents



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ID: 733985.0, MPI für bioanorganische Chemie / MPI für bioanorganische Chemie
Modulation of the CO2 fixation in dinickel azacryptands
Authors:Möller, Frauke; Castaneda-Losada, L.; Junqueira, J. R. C.; Miller, R. G.; Reback, M. L.; Mallick, B.; van Gastel, Maurice; Apfel, U.-P.
Language:English
Date of Publication (YYYY-MM-DD):2017
Title of Journal:Dalton Transactions
Journal Abbrev.:Dalton Trans.
Volume:46
Issue / Number:17
Start Page:5680
End Page:5688
Review Status:Internal review
Audience:Experts Only
Abstract / Description:While bimetallic azacryptands are known to selectively coordinate CO2, there is little knowledge on how different substitution patterns of the azacryptand cage structure influence CO2 coordination. Stopped-flow UV-vis spectroscopy, electrochemical analysis and DFT calculations were performed on a series of dinickel azacryptands and showed different rates of CO2 coordination to the complexes. We herein present data showing that the different flexibility of the azacryptands is directly responsible for the difference in the CO2 uptake capability of dinickel azacryptand complexes.
Comment of the Author/Creator:Date: 2017, MAY 7 2017
External Publication Status:published
Document Type:Article
Version Comment:Automatic journal name synchronization
Communicated by:N. N.
Affiliations:MPI für bioanorganische Chemie
Identifiers:ISI:000400424100025 [ID No:1]
ISSN:1477-9226 [ID No:2]
DOI:10.1039/c6dt04527h [ID No:3]
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