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          Institute: Fritz-Haber-Institut     Collection: Molecular Physics     Display Documents



  history
ID: 8381.0, Fritz-Haber-Institut / Molecular Physics
Valence and C 1s core level photoelectron spectra of camphor
Authors:Rennie, Emma E.; Powis, Iwan; Hergenhahn, Uwe; Kugeler, Oliver; Garcia, Gustavo; Lischke, Toralf; Marburger, Simon
Language:English
Date of Publication (YYYY-MM-DD):2002-09-24
Title of Journal:Journal of Electron Spectroscopy and Related Phenomena
Journal Abbrev.:J. Electron Spectrosc. & Relat. Phen.
Volume:125
Issue / Number:3
Start Page:197
End Page:203
Review Status:Peer-review
Audience:Experts Only
Abstract / Description:The valence photoelectron spectrum of camphor has been recorded with 95 eV synchrotron radiation, with better definition than previous He I spectra. The spectrum is interpreted by comparison with these He I results and with the aid of an outer-valence Green's Function calculation of the orbital ionization energies. These calculations closely reproduce the observed vertical ionization energies in the outer valence region. A core level spectrum of the C Is region (hv=357.9 eV) is also presented and reveals a marked shift of the carbonyl carbon relative to all others in the molecule.
Free Keywords:UV photoelectron spectrum; core level photoemission; Green's function ionization energies; camphor; IONIZATION ENERGIES; DERIVATIVES
External Publication Status:published
Document Type:Article
Communicated by:Gerard Meijer
Affiliations:Fritz-Haber-Institut/Molecular Physics
External Affiliations:Univ Nottingham, School of Chemistry, Nottingham, UK,
Max Planck Inst. for Plasma Physics, Garching, Germany
Identifiers:URL:http://www.sciencedirect.com/science?_ob=ArticleUR...
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